I am suggesting that there may be a non-zero voltage potential between your case and ground. Or between your case and your body. You may have to measure in A/C mode. You are probably in a low humidity environment and the case has been charged up via stray capacitance. The amount of charge stored is probably very small, but I cannot guarantee there isn’t a more serious (i.e. dangerous) fault in your PSU.
It looks like the PSU3 uses Meanwell IRM units which are marked with the “nested squares” icon of isolated supplies. I can’t say whether this isolation is maintained by Doepfer’s PCB design, but these isolated supplies are a common occurrence in eurorack and provide no electrical path to ground. So any static charge will linger until you give it another path to lower potential, like through your body.
Even a well-grounded and -bonded case can “shock” you… in those instances, you are providing the charge. Static is pretty harmless to healthy humans, but ESD is a real threat to poorly-designed or poorly-handled electronics.