Almost no hobbyist (and darn few module makers) owns a meter good enough to calibrate pitch CV to millivolt accuracy. You really need to spend $1k-ish on a new bench meter or (like I did) buy a really high quality vintage meter with calibration to get something good enough for the job.
The delay method @Galapagoose outlines above is what I use even though I own both that HP bench meter and an excellent universal counter. I don’t find a need to refine tuning further, but I start with one octave and work up to three or four while listening to beats.
You have to accept that your system might be .997V/octave when you’re done (unless your meter is good enough, you can’t verify the reference), and you have to pick your reference carefully–and make sure your other references can be calibrated too. Many quantizers in Eurorack aren’t even as good as an subpar guitar, tuning-wise, due to the widespread use of 12 bit DACs with high INL. Precision adders can be off also. Having designed and built a couple myself, I can tell you it’s harder that it looks to build a module that will reliably add or subtract 1.000V to CV signals under a range of supply voltages and output loads. You’ll also find that many pitch CV sources have some offset–this causes grief when you switch voltages in & out of precision adders and the like.
FWIW, my Mangrove exhibits the input offset behavior but tracks fine.
(Aside: I don’t know if I got a really special unit, but my Jones O’Tool+ agrees down to .001V with my HP3478A bench meter. This is shockingly good performance–better than my Fluke 87.)