As a general rule, you can only capture a system as a convolution if it is a linear time-invariant system. You can find a lot of descriptions of this property by searching. Briefly, it means that each sine component of the system’s input can be transformed into one or more sine components of the output at the same frequency, each at a different constant amplitude and delay time.
That “constant” is the real limiting condition here. In the case of the reverse reverb patches, the Midiverb is changing the amplitudes and delays of different parts of the patch, parts which make different output components, to get the overlapping backwards repeat kind of sound. With one constant IR you can’t reproduce this changing or the reverse effect.
In other patches, the Midiverb is modulating the times of the output components to get a smoother tail or a chorused quality. This stuff also can not be captured by convolving with an IR. So if some of the other reverbs also fall short of expectations as IRs, this is probably why.